European Journal of Molecular Biotechnology

11-22

Authors: Ignat Ignatov

We studied the mathematical model of interaction with water of natural mineral and microporous crystalline mineral ZEOLITH detox and ZEOLITH Creme of LavaVitae Company (Austria). In this report are submitted data about the interaction of ZEOLITH detox and ZEOLITH Creme with water, obtained by non-equilibrium (NES) and differential-equilibrium energy spectrum (DNES) of water. The average energy (∆EH... O) of hydrogen Н…O-bonds among individual molecules H2O after treatment of ZEOLITH detox with water measured by NES- and DNES-methods is ∆E=-0.0034±0.0011 eV for ZEOLITH detox. The average energy (∆EH... O) of hydrogen Н…O-bonds among individual molecules H2O after treatment of ZEOLITH detox with water measured by NES- and DNES-methods is ∆E=-0.0034±0.0011 eV for ZEOLITH detox. The average energy (∆EH... O) of hydrogen Н…O-bonds among individual molecules H2O after treatment of ZEOLITH detox with water measured by NES- and DNES-methods is ∆E=-0.007±0.0011 eV for ZEOLITH Creme. These results suggest the restructuring of ∆EH... O values among H2O molecules with a statistically reliable increase of local extremums in DNES-spectra. The research is performed for ZEOLITH detox with study of pH and oxidative reduction potential (ORP).

30-42

Authors: H.A. Shindy, A.K. Khalafalla, M.M. Goma, A.H. Eed

New heterocyclic starting material namely 4,5-dimethyl-2,7-diphenyl-furo[(3,2-d), ( -d)] bis pyrazole were prepared and employed to synthesis of some novel monomethine cyanine dyes (simple cyanine dyes) and trimethine cyanine dyes (carbocyanine dyes). Spectral sensitization evaluation for all the synthesized cyanine dyes was carried out through investigating their electronic visible absorption spectra in 95% ethanol solution. Solvatochromic and/or hachromic evaluation for some selected dyes were carried out through examining their electronic visible absorption spectra in pure solvents having different polarities [Water (78.54), Dimethylformamide (36.70), Ethanol (24.3), Chloroform (4.806), Carbontetrachloride (2.238) and Dioxane (2.209)] and/or in aqueous universal buffer solutions having varied pH values (1.75, 2.45, 4.65, 5.80, 7.88, 8.75, 10.85 and 12.60 units), respectively. Structure determination were carried out via elemental analysis, visible spectra. Mass spectrometer, IR and 1H NMR spectral data.