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Estimación de hidrocarburos aromáticos policíclicos y metales pesados asociados con la quema de caña de azúcar en el valle geográfico del río Cauca, Colombia
Authors: Diana Marcela Romero Cárdenas, Hugo Sarmiento Vela, Jorge E. Pachón
Number of views: 483
The present research assessed the presence of polycyclic aromatic hydrocarbons (PAH) and
heavy metals resulting from the burning of sugar cane in the Cauca River valley. For this purpose,
a subset of 240 samples was considered, integrated over 24 hours, of particulate matter of less than
10 microns (PM10), collected from October 2010 to February 2011 in the villages of Bolo San
Isidro (highly exposed zone) and Ricaurte (control zone) located in the municipalities of Palmira
and Bolivar. A chemical characterization related to the identification of HAPs belonging to the list
of priority contaminants of the United States Environmental Protection Agency was carried out
for part of the subset, following EPA T0-13A. In addition, the chemical characterization of metal
compounds in 108 of these samples carried out was taken into account, in accordance with the
EPA IO-3.1 method. The application of the principal components analysis (PCA), the factorial
analysis with varimax rotation and a series of statistical correlations allowed the identification of
the possible metals and PAH tracers of the burning of sugar cane. Results of the study show that
the PAH associated with the PM10 originated in the Cauca River valley, possibly attributed to the
burning of sugar cane in the high exposure zone, are: Pyr, Phe, and Flt, whereas the metals associated
directly and indirectly with this source of emission are: Fe, Mn, Si and Cu.