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Statistical Criteria for Modelling of Water Desorption Isotherms of Sugars. Estimation of Sucrose Hygroscopic Properties from Glucose and Fructose Data
Authors: Ramón Moreira, Francisco Chenlo, María D. Torres, Diego M. Prieto
Number of views: 441
Experimental water desorption isotherms of glucose, fructose and sucrose were determined at different temperatures (20, 35, 50, and 65ºC) using a static gravimetric method. Saturated salt solutions were selected to obtain different water activities from 0.09 to 0.91. All tested isotherms were type III following Brunauer’s classification. The experimental data were satisfactory fitted by Henderson and Iglesias and Chirife models. A complete statistical analysis was performed, determining that Henderson model was more suitable to fit the desorption isotherms of tested sugars, since it satisfied all the rejection criteria and showed, in all studied cases, the highest values of lumped measure for the goodness of fit. Predicted water desorption isotherms of sucrose from the experimental sorption isotherms of its individual monomers (glucose and fructose), in moles of water per mol oxygen, nicely matched with those obtained experimentally.