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Geochemical patterns of soils in the Bobov dol valley, Bulgaria. Assessment of Cu, Pb and Zn contents
Authors: Venera Tsolova, Ivona Nikova, Biser Hristov, Kalin Ruskov, Alexandar Zdravkov

Number of views: 345
The content of Si, Al, Fe, Ti, Mn, Mg, Ca, Na, K, S, P, C, Cu, Pb and Zn were
determined in order to reveal geochemical patterns of soils in the Bobov dol valley, Bulgaria.
Since the Bobov dol Thermal-electric Power Plant (TPP) is situated in the valley this paper
pays attention to the geospatial distribution of Cu, Pb, and Zn due to their diverse vital
significance. Elements assemblages and geospatial distribution pathways are also discussed
in the light of the past 40 years of operation of the Thermal Power Plant. According to the
results obtained the average content of Cu (27.04 mg kg-1
), Pb (21.96 mg kg-1
) and Zn (57.95
mg kg-1
) is higher than the average content of elements in local soil parent rocks: Cu (20.03
mg kg-1
), Pb (6.07 mg kg-1
) and Zn (46.60 mg kg-1
). Compared to the precautionary threshold
concentrations adopted for assessing the soil contamination in Bulgaria the elements contents
are lower including their maximum values. However, the geoaccumulation indexes reveal an
initial stage of contamination of soils with Pb. Lead tends to follow a separate mode of
geospatial distribution which is controlled by both the geogenic factors and the aerosol
emissions of TPP. Copper accumulation is more strongly affected by technogenic depositions
and dominated in urban and technogenic zones under the form of oval spots. Konyavska
Mountain is the domain of Zn revealing an altitudinal gradient of distribution. Its
accumulation proceeds slowly in topsoil, but still, Zn is the most abundant element in studied
soils from the Bobov dol valley. The petrogenetic pattern of geochemical suits still
predominated in studied soils wherein the iron has the greatest affinity for studied elements.
Soil medium reaction (pH) and organic carbon do not control the processes of distribution
and accumulation of Cu, Pb and Zn. The lack of statistical correlation with organic carbon
resulted from the siliciclastic nature of soil parent rocks and also reveals the prevailing
geogenic origin of studied elements.