Revista Ambiente & Água - An Interdisciplinary Journal of Applied Science

1-15

Authors: Alanna Maria do Nascimento Bezerra; Marcos Henrique Gomes Ribeiro; Artur Paiva Coutinho; Ana Emília Carvalho de Gusmão da Cunha Rabel; Elizabeth Amaral Pastich Gonçalves

Jean laundering generates significant effluent flows with a high organic load, color, and other pollutants, making it difficult to adjust effluent releases within legal limits. Slow Sand Filters (SSF) with downflow were tested for seven days (bench scale), to propose an after-treatment of effluents from an Effluent Treatment Plant of a jean laundry. The research evaluated the removal of the following parameters: color, turbidity, chemical and biochemical oxygen demand, conductivity, ammonia, total phosphorus and salinity of the textile effluent. The experimental apparatus had four SSF: the first filter was fed with distilled water, while the other three filters (triplicates) were fed with effluent. The filters had, on average, the following removal efficiencies: 91% for ammonia, 61.24% color, 89.43% turbidity, and 83.54% for phosphorus. Regarding the removal of organic matter, 98.11% for BOD and 81.17% for COD, demonstrating that SSFs were efficient in removing particulate, dissolved materials and organic matter.

1-11

Authors: Cristiane Patrícia Kist; Claudio Eduardo Scherer; Marlene Soares; Marcio Barreto Rodrigues

Pleurotus fungi are basidiomycetes that stand out in the degradation of recalcitrant organic compounds such as lignin derivatives and phenolic compounds. The aim of this study was to make a comparative evaluation of the capacity of the Pleurotus ostreatus POS 560 and Pleurotus floridae PSP1 fungi in the degradation of 2,4 and 2,6-dinitrotoluene (DNTs) in effluent from an explosive factory. The characterization of the effluent indicated 318 mg L-1 of DNTs, 246 mg L-1 of COD and toxicity factor for Daphnia magna corresponding to 8. The conduct of a multivariate study estimated the influence of the variables pH (5.0 and 6.0), co-substrate concentration (10 and 20 g L-1 of glucose) and species of the fungus Pleurotus (ostreatus and floridae) on the degradation of DNTs, indicating that the variables Fungus and [Glucose] were significant (p <0.05) presenting effects in the order of + 4.45 ± 0.26 and -1.14 ± 0.26, respectively. The reproduction of the best efficiency conditions (P. floridae; pH 6.0 and 10 g L-1 of glucose) in agitated flasks (100 rpm, 26oC) was able to carry out, within 14 days of treatment, the removal of organic matter and toxicity factor in levels on the order of 55 and 50%, respectively, in addition to the complete degradation of DNTs which occurred in the first 120 hours of treatment. In this period, the maximum activity of the peroxidase and Mn-peroxidase enzymes was also characterized, suggesting high potential of the bioprocess under study for remediation of effluents contaminated with nitroaromatic compounds.

1-10

Authors: Eduardo José Ludwig; Ubirajara Russi Nunes; Osmar Damian Prestes; Lovane Klein Fagundes; Tiéle Stuker Fernandes; Nathália Saibt

This study evaluated the physiological quality and quantified the efficiency of polymer in reducing the loss of phytosanitary products by leaching from soybean seeds of different diameters and in different treatments. Two lots of seed and two types of treatments were tested: polymers associated with seed treatment, and polymer application in layers after the seed treatment. For that, the following treatments were analyzed: Control= no seed treatment; Treat+pol= seed treatment + polymers in the mix; Treat/pol= seed treatment + polymers applied in layers; Treat= seed treatment. To evaluate seed treatment retention by the polymers, extraction equipment was employed and leaching of the active ingredient thiamethoxam was quantified. Evaluation of physical quality was conducted with tests of germination rate, first count, emergence rate, accelerated aging, seedling length, seedling dry mass and moisture content. Polymer application associated with seed treatment was efficient in reducing losses by leaching, reducing product loss by 20%. No significant differences in retention and physiological quality were found when different methods for polymer application were compared. Bigger seeds presented greater vigor, but the germination rate was unaffected.

1-12

Authors: Julia Aoki Domingues; Nelson Consolin Filho; Luiz Augusto Gomes de Souza; Flávia Vieira da Silva Medeiros

The use of natural coagulants is a promising alternative to replace or assist chemical coagulants due to its numerous advantages. This paper evaluates the effectiveness of a natural coagulant in water treatment. The coagulant was extracted from the Zygia cauliflora (Willd.) Killip seed in saline solutions and defatted using 95% ethanol. The tests were conducted using different concentrations of the coagulant (0.1, 0.5, 1.0, 2.0, 3.0, and 4.0 g L-1) and of NaCl (0.0 M, 1.0 M, and 5.0 M). The results showed that the use of 2 g L-1 of coagulant and 1.0 M of the salt achieved an effectiveness of 20% and 70%, respectively, of color and turbidity removal. The analysis showed an effectiveness of 70% and 30%, respectively, when removing the UV254 compound and DOM (dissolved organic matter). The mechanism for turbidity removal by the coagulants prepared with aqueous solution and with saline solution at 1.0 M of NaCl is supposed to be adsorption and charge neutralization, respectively, following the Freundlich and Langmuir models. However, the coagulant prepared with saline solution at 5.0 M of NaCl tends to form a netlike structure followed by turbidity removal through a sweep coagulation mechanism. Future papers should therefore focus on the use of Zygia cauliflora (Willd.) Killip as an alternative for replacement or use as an auxiliary chemical coagulant.

1-15

Authors: Francisco Wellington Martins da Silva; Cleiton da Silva Silveira; Antônio Duarte Marcos Junior; João Dehon de Araujo Pontes Filho

The Brazilian energetic matrix is predominantly based on hydroelectric plants and its planning is very sensitive to climate variability in different time scales. Natural Affluent Energy (NAE) is an established planning tool to project different scenarios of possible energy production, especially in an integrated system. This work aims to fill a gap between short-term (seasonal/ interannual) and long-term (climate change) planning scales by realizing NAE medium-term projections for the Brazilian National Interconnected System basins. The historical NAE series provided by the National System Operator was used for the years 1931 to 2014. The series was divided into two periods: from 1931 to 2003 for verification, and from 2004 to 2014 for calibration. The Wavelets Auto-Regressive (WAR) model was applied from low- and medium-frequency bands. The band signal was analyzed and the NAE was projected for the years 2014 to 2024. A relationship of the NAE variability with the Pacific Decadal Oscillation (PDO) climate index and the Atlantic Multidecadal Oscillation (AMO) was verified.

1-10

Authors: Érica Aparecida Batista; Luane Ferreira Garcia ; Antonio João Carvalho de Albuquerque; Nara Ballaminut; Paulo Sérgio Scalize; Eric Souza Gil

The chemical and pharmaceutical industries are the main generators of residues, such as phenolic microcontaminants, including catechol, resorcinol, p-nitrophenol and 4-chlorophenol. Therefore, this work aims to identify these microcontaminants through an emerging contaminant biosensor by means of an enzymatic biosensor constructed with an enzymatic extract from the fungus Marasmiellus colocasiae. Based on the differential pulse voltammetry electrochemical technique, the biosensor was used to analyze the patterns of catechol, resorcinol, p-nitrophenol and 4-chlorophenol. The analysis of a sample prepared with these standards in water from the public supply network was also carried out. As a result, it was possible to verify that the biosensor developed in this study is more sensitive than conventional methods and has a greater affinity for catechol. In the sample prepared with the standards, it was possible to qualitatively identify the presence of 4-chlorophenol, resorcinol and catechol. The proposed biosensor was sensitive and has potential for application in the analysis of microcontaminants in the environment with the detection limit = 0.17 µmol L-1, and the quantification limit = 0.52 µmol L-1.