Iranica Journal of Energy and Environment (IJEE)

1-6

Authors: K.H. Bhujangrao

Today’s India is in need of generating power at higher rate to maintain adequate supply of electricity to users for development and growth of Nation. Non renewable energy sources like coal and petroleum products are the major sources utilized for power production. To reduce the gap between demand and supply of energy and maintain sustainable development, renewable energy sources need to be considered as an alternative source of energy. The solar energy has been identified as one of the promising energy source which can be used directly or indirectly for generation of electricity, hot water and power. A prototype of cylindrical parabolic collector (CPC) is designed and developed to utilize solar energy for hot water generation. Prototype of CPC is tested from 10AM to 4PM in the month of May and thermal performance is evaluated based on solar standards available through literature. Hot water at 600C is produced throughout a day by varying mass flow rate of water. The instantaneous efficiency is calculated after every half an hour and found to be 69% and overall efficiency of system is 71%. This prototype CPC system can deliver hot water at required temperature to meet industrial, domestic demands and saves electricity.

12-17

Authors: Sanjay Mohite, Sudhir Kumar, Sagar Maji, Amit Pal

Karanja and linseed are the potential non-edible oil crops which can be used for the biodiesel production. The main objective of this study is to find out the feasibility of using a mixture of karanja oil and linseed oil to produce biodiesel. Karanja oil has high amount of free fatty acid in it and linseed oil has low amount of free fatty acid content. Karanja biodiesel is produced by two step esterification/transesterification process which is costly, health hazardous & corrosive due to use of concentrated acids. Linseed biodiesel can be produced by alkali-base transesterfication which is much faster and gives higher yield than acid-base transesterification. A production method is developed to produce biodiesel from the mixture of karanja and linseed oil which is faster, safer and non-corrosive. The yields in the range of 68.2 to 78.9% have been achieved with varying different parameters like molar ratio, stirring time, mixture ratio and amount of catalyst. Optimum parameters are also established to achieve maximum biodiesel yield from the transesterification of a mixture of linseed and karanja oils.

31-38

Authors: Claire Xin-Hui Su, Tjoon Tow Teng, Norhashimah Morad and Mohd Rafatullah

A novel inorganic-organic hybrid polymer of magnesium chloride-polyethylene oxide (MgCl2-PEO) was prepared, characterised and applied in the coagulation-flocculation of a reactive dye, Cibacron Blue F3GA (RCB). The hybrid polymers were prepared in various ratios and their conductivity and viscosities were measured. For the application in the coagulation-flocculation of RCB, the hybrid polymer of 90% MgCl2:10% PEO ratio was selected as it showed the highest conductivity and lowest viscosity. The factors that affect coagulation-flocculation of RCB, namely initial dye concentration, initial pH, agitation speed, agitation time and hybrid polymer dosage, were studied using fractional factorial design and response surface methodology (RSM). The process was also optimised, with respect to colour removal and chemical oxygen demand (COD) reduction efficiency. The five factors studied showed significant effects toward the colour removal and COD reduction of RCB. The process was optimum at initial dye concentration of 173 mg/L, pH 11.13, agitation speed of 150 rpm, agitation time of 6 minutes and hybrid polymer dosage of 1020 mg/L. Under these optimum conditions, maximum colour removal of 99.76% and COD reduction of 92.09%, were achieved.

48-51

Authors: Imoisili Patrick Ehi, Jiddah-Kazeem, Bidemi, Yahaya L. E.

The kinetic and characteristics of water absorption of cocoa-pod husk filler reinforced epoxy composite by short-term immersion at room temperature was studied. Composite specimen containing 5, 10, 20 and 30% filler volume fraction were prepared. The percentage of moisture uptake increased as the fibre volume fraction increased due to the high cellulose content of cocoa-pod husk. Results indicate that a D value of 105.8 x 10-7 m2/s at 30% volume fraction was obtained.The process of absorption of water was therefore found to follow the kinetics and mechanism described by Fick's law.

58-63

Authors: L.E Yahaya, A.K Akinlabi

The adsorption of lead (II) ions onto EDTA- modified cocoa pod husk (CPH) in an equilibrium system was investigated. Kinetics, mechanism and thermodynamic parameters were estimated. Adsorption capacity was rapid and time dependent as appreciable level of Pb (II) uptake was achieved at an optimum contact time of 50 minutes. Three kinetic models were used to fit the kinetic data; Pseudo-first order, Pseudo-second order and intraparticle diffusion. Adsorption of the metal ions follows the Pseudo-second order and intraparticle kinetics as these provide a better fit to the experimental data with high R2 values ranging from 0.9776 – 1. Thermodynamic parameters such as change in Gibbs free energy ( ∆Go ) change in enthalpy (∆Ho), and entropy change (∆So ) were calculated. The ∆Go (-5.499kJmol-1), ∆Ho (60.36 kJmol-1) and ∆So (212.44 Jmol-1K-1) of the adsorption process of metal ions onto the modified adsorbent was found to be feasible, endothermic, spontaneous and physiosorption in nature. These results indicate that modified CPH is a promising sorbent for the removal of Pb (II) in industrial effluent and wastewaters containing same.

72-83

Authors: Islam M. Rafizul, Muhammed Alamgir

This study illustrates the leachate treatment efficiency based on leachate pollution index (LPI) of pre-treatment leachate as well as post-treatment leachate with chemical coagulants. Leachate samples were collected at regular intervals of time from the leachate collection chamber of the landfill lysimeter at KUET campus, Bangladesh to compute its pollution potential. The landfill lysimeter consists of one open dump lysimeter-A with leachate detection (A1) and collection system (A2) as well as two sanitary landfill lysimeters B and C having two different types of cap liner. The relevant parameters of leachate sample were measured in the laboratory to evaluate sub-pollution (sub-LPIs) in terms of LPI in organic pollutant (LPIor), inorganic pollutant (LPIin) and heavy metal (LPIhm) as well as the overall LPI. Moreover, the values of LPI in pre-treatment leachate were to be found 19.53, 25.33, 23.48 and 23.74 for the A1 and A2 systems of open lysimeter-A, as well as the collection systems of sanitary lysimeters-B and C, respectively. It reveals significantly the higher values than that of LPI of 5.77, 7.38 and 7.38 for the maximum leachate discharge standards of Bangladesh, India and Hong Kong, respectively. The leachate was then treated with ferric chloride (FeCl3), poly alluminum chloride (PAC), ferrus sulphate (FeSO4) and aluminum sulphate (Al2(SO4)3) in various dosages and pH values. The concentrations in post-treatment leachate by using FeCl3 at optimum dosage were to be found below the limit of maximum leachate discharge standards. Study also reveals the values of LPI of 5.32, 5.69, 5.32 and 5.24 in post-treatment leachate for the A1 and A2 systems of open lysimeter-A, as well as the collection systems of sanitary lysimeters-B and C, respectively below the values of LPI in leachate of maximum discharge standards. Finally, it can be concluded that differences in the level of contaminants of pre-treatment and post-treatment leachate indicated the role of leachate treatment system in minimizing the level of contaminants and lowering the risk of leachate contamination based on LPI.