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Comparison of Three Polypyrrole-Cellulose Nanocomposites Synthesis
Authors: Benoit Bideau, Eric Loranger , Claude Daneault
Number of views: 487
In this study, composite films based on TEMPO-oxidized cellulose nanofibers (TOCN),
and polypyrrole (PPy) were synthesized by three different processes. The flexible composite films
were investigated with scanning electron microscopy, thermogravimetric analysis, contact angle
measurements, and finally, by mechanical and electrical testing. The developed composites have
shown interesting mechanical properties (TOCN/PPy-3) as Young modulus (6.35 GPa) and tensile
stress (65.6 MPa) or electrical conductivity (TOCN/PPy-1; 51.6 S/cm) for further applications such
as flexible electrode. From proposed methods, the grafting of N-(3-aminopropyl)pyrrole was also
interesting because it presented intermediate properties from all composites, and could represent a
good compromise between the mechanical and electrical properties. Depending of their final
application and by choosing an appropriate fabrication method, these composites could be considered
in the design of high-performance electrodes for supercapacitor, battery, sensor or various packaging.